CONTENTS

Front Matter

Title Page, Preface and Acknowledgements
About the Author
Status, History, Issues and Updates
Complementary Textbooks
Teaching Notes and Resources
A Note about Numerical Solutions

Course Units

I. Chemical Reactions
1. Stoichiometry and Reaction Progress
2. Reaction Thermochemistry
3. Reaction Equilibrium
II. Chemical Reaction Kinetics
A. Rate Expressions
4. Reaction Rates and Temperature Effects
5. Empirical and Theoretical Rate Expressions
6. Reaction Mechanisms
7. The Steady State Approximation
8. Rate-Determining Step
9. Homogeneous and Enzymatic Catalysis
10. Heterogeneous Catalysis
B. Kinetics Experiments
11. Laboratory Reactors
12. Performing Kinetics Experiments
C. Analysis of Kinetics Data
13. CSTR Data Analysis
14. Differential Data Analysis
15. Integral Data Analysis
16. Numerical Data Analysis
III. Chemical Reaction Engineering
A. Ideal Reactors
17. Reactor Models and Reaction Types
B. Perfectly Mixed Batch Reactors
18. Reaction Engineering of Batch Reactors
19. Analysis of Batch Reactors
20. Optimization of Batch Reactor Processes
C. Continuous Flow Stirred Tank Reactors
21. Reaction Engineering of CSTRs
22. Analysis of Steady State CSTRs
23. Analysis of Transient CSTRs
24. Multiple Steady States in CSTRs
D. Plug Flow Reactors
25. Reaction Engineering of PFRs
26. Analysis of Steady State PFRs
27. Analysis of Transient PFRs
E. Matching Reactors to Reactions
28. Choosing a Reactor Type
29. Multiple Reactor Networks
30. Thermal Back-Mixing in a PFR
31. Back-Mixing in a PFR via Recycle
32. Ideal Semi-Batch Reactors
IV. Non-Ideal Reactions and Reactors
A. Alternatives to the Ideal Reactor Models
33. Axial Dispersion Model
34. 2-D and 3-D Tubular Reactor Models
35. Zoned Reactor Models
36. Segregated Flow Models
37. Overview of Multi-Phase Reactors
B. Coupled Chemical and Physical Kinetics
38. Heterogeneous Catalytic Reactions
39. Gas-Liquid Reactions
40. Gas-Solid Reactions

Supplemental Units

S1. Identifying Independent Reactions
S2. Solving Non-differential Equations
S3. Fitting Linear Models to Data
S4. Numerically Fitting Models to Data
S5. Solving Initial Value Differential Equations
S6. Solving Boundary Value Differential Equations

Unit 21. Reaction Engineering of CSTRs

This website provides learning and teaching tools for a first course on kinetics and reaction engineering. Here, in Part III of the course, the focus is on the modeling of chemical reactors. In particular, it describes reaction engineering using the three ideal reactor types: perfectly mixed batch reactors, continuous flow stirred tank reactors and plug flow reactors. After considering each of the ideal reactor types in isolation, the focus shifts to ideal reactors that are combined with other reactors or equipment to better match the characteristics of the reactor to the reactions running within it.

Section C of Part III examines reaction engineering for continuous flow stirred tank reactors (CSTRs). As was done for batch reactors in the previous section of the course, common reaction engineering tasks are identified and the qualitative performance of CSTRs is examined. CSTRs are typically designed to operate at steady state, but getting them started and shutting them down involves transient operation. The mathematical analysis of transient reactors differs from that for steady state reactors, so these two situations are presented separately. In addition, CSTRs can display a phenomenon known as multiplicity of steady states which is discussed in this section.

Unit 21 introduces the topic of reaction engineering for CSTRs. It describes how to qualitatively analyze a CSTR, with an emphasis on the differences between CSTRs and batch reactors. It also distinguishes between steady state operation and transient operation. It is critically important to be able to make this distinction when solving problems involving CSTRs in subsequent units.

Learning Resources

  • Archive (.zip) - Contains all learning resources listed below (except simulators) for this unit
  • Documents to Read:
  • Videos to Watch (please right-click and save, then play back locally on your computer):
  • Reference Files:
  • Simulators  
    Please note that these simulators are intended for educational purposes only. They should not be used for any other purpose, and if they are, the author does not bear any responsibility or liability for the consequences.
     
    The “zipped .jar file,” when unzipped, will produce a folder that contains a .jar file and a folder named "lib". Not surprisingly the latter folder contains additional libraries and files that the simulator uses. To run the simulator, launch the .jar file either from the command line using java -jar [name of .jar file], or by double clicking it if your operating system supports it. The simulators require JAVA 1.6 or later in order to run. There is a User's Guide under the Help menu that describes how to use the simulators.
     

Teaching Resources

  • Archive (.zip) - Contains all teaching resources listed below (except simulator source files) for this unit
  • Sample Class
  • Simulator Source files  
    Please note that these simulators are intended for educational purposes only. They should not be used for any other purpose, and if they are, the author does not bear any responsibility or liability for the consequences.
     
    The “Netbeans Project folders” contain the Netbeans java project used to create them. Providing them in this way will allow instructors or students familiar with java and the Netbeans development environment to modify them. They were developed using version 6.7 of Netbeans. They use the Swing Application Framework, which is not supported in version 7.1 or higher of the Netbeans IDE. They are no longer in development, and I am not available to consult on any issues encountered when using them.

Practice Problems

to be added.